A |
Acceptor:
A substance that is able to accept a proton
Acid:
A substance that is able to donate protons and in turn increase
the concentration of hydrogen ions when dissolved in water.
Acid
dissociation constant: Ka, the equilibrium constant for a
reaction in which a proton is removed from an acid
Acidic:
A solution that has a greater concentration of hydrogen ions
than hydroxide ions
Acidic
solution: A solution that has a greater concentration of
hydrogen ions than hydroxide ions
Acid-base
pair: An acid and a base pair, which only differs in the
presence or absence of a proton, such as hydroxide and water
Amphoterism:
Amphoterism refers to the ability for certain oxides and hydroxo
compounds to act either as acids or bases
Anion:
An anion is a negatively charged ion
Aqueous:
A solution in which water is the solvent
Aqueous
solution: A solution in which water is the solvent
Arrhenius:
He formulated the theory of acids and bases based on the
production of hydrogen ions and hydroxide ions in aqueous
solution
Arrhenius
definition: An equation that relates the rate constant for a
reaction to the frequency factor, the activation energy, and the
temperature
Autoionization:
The process whereby water spontaneously forms low concentrations
of hydrogen and hydroxide ions by proton transfer from one water
molecule to another
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B |
Base:
A substance that produces an excess of hydroxide ions when it
dissolves in water; a hydrogen ion acceptor
Basic:
A solution that has a greater concentration of hydroxide ions
than hydrogen ions
Basic
solution:
A solution that has a greater concentration of hydroxide ions
than hydrogen ions
Bronsted-Lowry:
The two chemists who formulated the theory of acids and bases in
terms of proton donors (acids) and proton acceptors (bases)
Bronsted
acid:
Any substance that acts as a source of protons
Bronsted
base:
Any substance that acts as a proton acceptor
Buffer:
A buffer solution resists or suppresses a change in its pH on
addition of small amounts of acid or base
Buffer
capacity:
The amount of acid or base that a buffer can accept without the
pH changing appreciatively, determined by the magnitude of [HA]
and [A-] in the solution
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C |
Cation:
A
cation is a positively charged ion, which migrates toward the
cathode in an electrochemical cell
Common
ion effect:
It is the shift in equilibrium that occurs when an ion already
present in the equilibrium reaction is present or added
Concentration:
The quantity of solute present in a given quantity of solvent or
solution
Conjugate
acid:
The substance formed by addition of a proton to a base
Conjugate
acid-base pair:
An acid and a base, which only differ in the presence or absence
of a proton, such as acetic acid and acetate ion or hydroxide
and water
Conjugate
base:
Everything that remains of the acid molecule after a proton is
lost
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D
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Dilution:
The process of reducing the concentration of a solution by
adding more solvent
Donor:
A substance being able to give away a proton
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E |
Electron
drift: It occurs when electrons are attracted by highly
electronegative atoms away from bonded OH ions which in turn
further polarizes and weakens the O-H bond, making a stronger
acid
Electro
negativity:
Electro negativity is a measure of the electron attracting power
of an atom; metals have low electro negativities, and non-metals
have high electro negativities
Equilibrium:
the dynamic state where the concentrations of all reactants and
products remain constant with time
Equilibrium
constant:
the value obtained from the product of the concentrations of all
the reaction products, each raised to the power of its
coefficient in the balanced equation, divided by the product of
the concentrations of the reactants, each raised to the power of
its coefficient in the balanced equation
Equivalence
point:
The point in a titration when enough titrant has been added to
react exactly with the substance in solution being titrated
(analyzed)
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H |
Henderson
Hasselbalch equation: An equation giving the pH of a
solution containing a mixture of a weak acid and its conjugate
base
Hydrolysis:
The term given to acid-base reactions in aqueous solution in
which ions act as acids or bases.
Hydronium
ion:
a hydrated proton, H3O+
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I |
Ion:
Electrically charged atom or group of atoms, which can be
positively or negatively, charged depending on whether electrons
are lost or gained by the atoms
Ion
product constant:
Kw, the product of the concentration of hydrogen ions and the
concentration of hydroxide ions in an aqueous solution
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K |
Ka:
The acid dissociation constant. The equilibrium constant for the
reaction of an acid dissociating into its conjugate base and the
hydronium ion
Kb:
The base dissociation constant. The equilibrium constant for the
reaction in which a base reacts with water to produce its
conjugate acid and the hydroxide ion
Kc:
It is the relationship that exists among the molarity
concentrations of the reactants and products in a reversible
reaction at equilibrium
Ksp:
It is the solubility product constant
Kw:
The ion product constant. It
always refers to the autoionization of water, and is equal to 1
x 10E-14 at 25 degrees Celsius
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L |
Lone
pair: A pair of electrons found in the valence shell of an atom,
which is not involved in bond formation
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M |
Minute:
A very small quantity of substance
Molecule:
Is a group of bonded atoms that exists as separate entity and
has characteristic physical and chemical properties
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N |
Neutral:
A solution that has an equal concentration of hydroxide and
hydrogen ions
Neutral
solution:
A solution that has an equal concentration of hydroxide and
hydrogen ions
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P |
pH:
A convenient way of representing the concentration of hydronium
or hydrogen ions in a solution. It is defined as the negative
log of the concentration of hydronium ions
pOH:
A convenient way of representing the concentration of hydroxide
ions in a solution. It is defined as the negative log of the
concentration of hydroxide ions
pH
scale:
A scale ranging from 1 to 14 rating the strengths of acids and
bases defined by their pH value. The closer to the ends of the
scale, the stronger their strength, whereas the closer to the
center of the scale the more neutral they are
Polarity:
It describes the ease with which the electron cloud in an atom
or molecule can be distorted in an electric field
pK:
A convenient way of representing an ionization constant. pK
values are useful when comparing the relative strengths of acids
(pKa) and bases (pKb)
Process:
A method to complete an objective
Proton:
Fundamental particles carrying the basic unit of positive
electric charge and found in the nuclei of all atoms
Proton
acceptor:
An atom that is able to accept a proton from another atom;
another name for the hydrogen ion, H+
Proton
donor:
An atom that is able to donate a proton to another atom or
proton acceptor
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Q |
Qualitative
analysis: It determines the presence or absence of a
particular metal ion
Quantitative
analysis:
It determines how much of a given substance is present
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R |
Reaction:
Set of elementary steps or processes by which a reaction is
proposed to occur. The mechanism must be consistent with the
stoichiometry of the net equation and with the rate law for the
net reaction.
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S |
Solubility
product constant: It describes the equilibrium in a
saturated solution of a slightly soluble compound
Soluble:
A substance that can dilute and dissociate itself in the
presence of water thus becoming a solution
Solution:
A solution is the liquid or aqueous form of reactants or
products
Standard
solution:
a solution of known concentration
Stoichiometric:
It refers to the quantitative measurements and relationships
involving substances and mixtures of chemical interest
Stoichiometric
point:
The point in a titration when enough titrant has been added to
react exactly with the substance in solution being titrated
(analyzed)
Strong
acid:
An acid that is completely ionized in aqueous solution
Strong
base:
A base that is completely ionized in aqueous solution
Substances:
A substance has constant composition and properties throughout a
given sample and from one sample to another. All substances are
either elements or compounds
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T |
Titrant:
the substance in a titration, which is added gradually to the
solution being analyzed
Titration:
A process in which the concentration of an unknown solution (of
acid or base) can be determined by reacting a measured quantity
of the unknown solution with a measured volume (of acid or base)
of known concentration
Titration
curves:
A titration curves is a graph of solution pH versus volume of
titrant. It outlines how pH changes during and acid-base
titration, and it can be used to establish such features as the
equivalence point of the titration
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W |
Weak
acid: An acid that is only partially ionized in aqueous
solution
Weak
base:
A base that is only partially ionized in aqueous solution
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